Alcoholic beverages

 

Beverages

 

          Alcoholic Beverages

·         Beer

·         Wine

·         Spirits

          Non-alcoholic beverages

·         Flavoured beverages

·         Hot Drinks

·         Coffee

·         Tea

·         Other drinks

          Chocolate based

          Soft Drinks

·         Carbonated beverages

·         Fruit/vegetable juices

·         Bottled water

·         Functional Drinks

·         Ready-to-drink concentrates

·         Ready-to-drink teas

 

 Beer production







a)      Malting

Malt is barley that has been persuaded to germinate by soaking in water and has then been dried by the application of heat .

The “Steeping” or soaking period in the tank is usually 2 to 3 days.

The water is drained off and the grain spread out to a depth of 20–30 cm on a concrete or tiled floor in the malting house.

The water content of the barley rises to approximately 43% by this soaking or steeping process. Barley begins to germinate on the malting floor and generates energy that raises the temperature. The barley must be turned every 4 or 6 h in order to maintain approximately 168C temperature and to prevent growing roots tangling each other.

After 7 to 10 days, the growing stem of the barley becomes one-half to five-eighths of the length of the seed .

To stop the germination, green malt is transferred to the drying kiln, which has a unique chimney

The floor of the kiln is a drain board made of perforated iron or wire mesh. The green malt is spread on this floor at a depth of 70 cm to 1 m, depending on the design of the kiln, and dried in smoke rising from a peat fire below the floor .Besides peat, coal and coke are often used as fuel and the barley is dried for 40–55 h until the moisture content becomes 3–4%.

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b)      Malt Milling

                By milling malt, the starchy endosperm will become better accessible for the malt enzymes and this will improve the extraction process.

                The selected milling technique depends on the methods of mashing and separation that are used.

                Milling should be performed in conditions that preserve the structure of the husks when a lauter or mash tun is used, as in this case the husks are needed to build up the filtration bed.

                The husks are more elastic and will be less damaged during milling when they are more humid. Therefore, the malt is usually made humid (called “conditioned” or “wet” milling) before it is milled. Dry or wet milling is performed in a roller mill.

 

Type of Milling

          Dry milling

          Wet milling

          Milling with Conditioning

 

Dry milling

Roller and hammer mills can be used for dry grinding. Rolling mills operate by passing the malt through the narrow gap between pairs of closely spaced rotating rolls

Oscillating (frequency of 6–12 Hz) sieves perform the separation steps.

 

Wet milling

§   The moisture content of the husks can be raised to 20% by keeping the endosperm nearly dry in a hot water conditioning mill. This process is referred to “hot water conditioning”

§   In this case, the endosperm is squeezed from the husk through a single pair of rolls.

§   After milling, mashing water is immediately added. The quantity of conditioning water depends on the malt quality, degree of modification, and achieved steeping degree.

 


Milling with Conditioning 

§    In this process, the malt is moisturized with cold or hot water, or steam. Moist husks are more pliable and will be less damaged in a roll mill.

§    The temperature inside the kernel may not exceed 40 ° C to avoid damage to the enzymes. The total water content increases by about 0.7%. This corresponds to an increase in water content of the husks of 1.5–1.7% and 0.3–0.5% of the endosperm.

§    The effect of the conditioning results in an increase of the husk volume of about 10– 20%, an easier separation of the grist and husks fraction, an increase in filtration rate in a lautertun, an increased yield and attenuation, and a faster starch degradation.


 

c)      Mashing

§    Mashing starts with mixing the grist and brewing water (called “mashing-in”).

§    Hydration enables the malt enzymes to become active. Today, mashing-in is part of the milling process, where it is performed in the milling equipment. Typically, 2–4 hL water is used for 100 kg malt, depending on the selected brewing method and density of the produced beer.

§    During mashing, the malt content is solubilized by making use of the enzymes of the malt and the extract is obtained . The mashing operation will influence the alcohol content of the beer, the concentration of unfermented sugars in the beer, the peptide and amino acid profiles of the wort, the yeast nutrient concentration, the buffering capacity and pH of the wort and beer, the b-glucan content of the beer, and some beer physical properties such as foam, color, and clarity.


 

 

Mashing Methods

§   Mashing is performed in a mashing vessel (also called mashing tun, mash mixer, or mash converter):

 

Ø  45–50° C for proteolysis and b-glucan degradation;

Ø  62–65° C for maltose production (b-amylase);

Ø  70–75° C for saccharification (a-amylase); and 78° C as the final mash temperature to inactivate the carbohydrate enzymes and fix the amount of fermentable sugars

 

Two types of mashing methods:

          Infusion Method

          Decoction Method

Infusion Method

§    In infusion processes, the entire mash is heated up (with appropriate rest periods) to the final mashing temperature.

§    Infusion methods can be classified as increasing temperature (German infusion method) and decreasing temperature (English infusion method) infusion processes (Fig. 20.3 shows some examples).

§    A classical German infusion method starts with a rest period at 45–50 ° C (proteolysis) for 30 min. Next, the temperature is raised to 62–65 ° C and kept at this temperature for 30–45 min (b-amylase). The next rest period is at 70–75 ° C until complete saccharification (a-amylase). The process ends at 78 ° C.

§    In the English infusion method, the temperature is initially raised by adding hot water to the mash. This method requires well-modified malt, because a part of the active enzymes are destroyed by the addition of hot water. An alternative English method is to perform the conversion processes at a single temperature, usually 63–65 ° C (“isothermal infusion mashing”). These English infusion methods are used for the production of ales (top fermentation), where both mashing and wort separation take place in the same vessel (O’Rourke 1996).

§    The advantages of the infusion method are that this process can be easily automated and controlled, and energy consumption is 20–30% lower than for the decoction method (Kunze 1999). Disadvantages are the rather worse iodine reaction and the possibly rather lower brewhouse yield

 

 

Decoction Method

§   In decoction processes, the temperature is increased by moving part of the mash from the mash converter to the mash cooker where it is boiled (possibly also with carbohydrate rest periods in the mash cooker).

§   By pumping it back to the remainder of the mash in mash converter, the temperature of the total mash is increased to the next higher rest temperature. The decoction method is traditionally used in Germany for the production of lager beer.

§   Depending on the number of boiled mashes, decoction methods can be classified as single-, two-, and three-mash processes. Today, only the single- or two-mash processes are used. The three-mash process consumes a lot of energy and is only used for the production of some special beers.

 

 
The removal and boiling of the boiled mashes have the following effects:

            Less protein breakdown in the boiled mash because of           more rapid heating;

            More extensive gelatinization and saccharification of the starch;

            Increased extraction of the husks;

            Increased formation of melanoidins (Maillard reaction);

            Increased removal of dimethyl sulfide (DMS);

            Reduced amounts of active enzymes in the total mash; and

            Possibly a higher brew house yield

 

 

Mashing schemes

 

 


 

 

       


Increasing infusion mashing

 

 

 


 

Decreasing infusion mashing

 

 


                                                   

 

 

 

 

 

 

Two mash decoction process.


 

Enzymatic Degradation Processes

          Starch Degradation

          Cell Wall Degradation

          Protein Degradation


Starch Degradation

§   Starch is degradated by alpha- and beta-amylase, limit dextrinase, maltase, and saccharine.

§   Gelatinized starch is needed for beta-amylase in order to degrade starch efficiently.

§   The complete degradation of starch to maltose and dextrines by amylases is called saccharification.

§   Starch breakdown must be monitored because residues of undegraded starch and dextrins cause starch hazes in beer.


Cell Wall Degradation

·        Cell walls are essentially composed of b-glucan and hemicellulose.

·        Cell wall degradation starts during malting and continues during mashing by endo-b-glucanases, b- glucansolubilase, and endo-xylanase

·        An insufficient degration of high-glucan molecules results in a high viscosity and can give problems during wort and beer filtration

·        An insufficient degradation of pentosans (hemicellulose) can result in filtration and haze problems.


Protein Degradation

§    Protein degradation products influence fermentation and beer flavor (lower molecular weight (MW) degradation products), palate fullness (amino acids and higher MW degradation products), color (Maillard reaction), and beer foam (higher MW degradation products).

§    A too extensive proteolysis gives bad foam, too dark color, poor palate fullness, but a good colloidal stability. During malting and mashing, 35–40% of the total protein content is degraded.

§    The enzymatic breakdown of proteins occurs predominantly at 45–55 ° C, but does not stop even at higher temperatures.

 

d)      Wort Separation (Lautering)

§    During the lautering process (also called “wort separation” or “mash separation”) the un-dissolved substances are separated from the wort.

§    The insoluble part (spent grains) consists of the husks, the seedlings, and other insoluble material.

§    Wort separation is a filtration process. As much of the extract as possible should be recovered during lautering.

§    The extraction efficiency is measured as “extract yield”, which is the ratio of the mass of extract to the mass of malt or malt and adjunct.

§    The filtration can be performed in a lautertun or a mash filter. Developments in wort separation, which have been introduced over the last 15–20 years


 

 

e)      Fermentation

Yeast is added in liquid or solid form to the wort and fermentation takes place at 17–35 ° C for 48 h (on average).

The inoculated yeast converts maltose into glucose, and then alcohol and carbon dioxide (CO2) are produced from glucose.

Yeast also produce small amounts of other compounds such as a wide range of esters, aldehydes, acids, and higher alcohols. Many of these are flavor elements. The fermented wort (wash) is a sweet peaty beer-like liquid with an alcoholic content of 7–8%.

 

 

f)       Filtration

This is to remove yeast which otherwise continue the process of fermentation.

 

g)      Pasteurization
For beer making, the filtrate needs to be heat treated to destroy pathogens before bottling. Beer is packaged in dark bottles or in amber, to prevent light destruction of the beer.
 
 
** For whisky production:
**Types of whiskey: scotch, grain and blended whisky
 

h)      Distillation

 Distillation is what actually produces the whisky.

Done in onion-shaped stills (pot stills), which are large copper kettles with narrow necks called lyne arms or lyne pipes that curve and enter the condenser, often located in the open air outside the still house .Copper dissolves easily and has a decisive influence on the quality of the spirit, as it removes sulfury or vegetable aromas by a chemical reaction

 

i)        Maturation

 The immature spirit, called new pot or new spirit, is piped to the filling station, where it is diluted with water until its strength is reduced to 63.5% by volume of alcohol.This diluted spirit is stored in casks made either from American white oak (Quercusalba) or European oak (Quercusrobur) for maturation. Oakwood is thought to be desirable for maturing whisky because of its chemical complexity.

The casks are secondhand, in that they have been used to store either sherry or bourbon, and in rare cases port or other wines.

Maturation of new spirits is conducted in casks stored in warehouses called “dunnage” warehouses for at least three years undisturbed. After that they can be legally called scotch whisky.

 

 

j)        Bottling

 Before bottling, whisky is further diluted with water until its strength is reduced to 40–60% by volume of alcohol. Whisky is usually filtrated through a cellulose filter to remove fatty particles at a temperature between 4 and 10 ° C prior to being run into bottles. Once run into the bottles, whisky does not further mature, but some chemical changes will occur. Single malt whisky is the product of a single distillery.

 

 

**Wine may be defined as a fermented beverage prepared from grapes after alcoholic fermentation. When other fruits are used for preparation of wine then these are called by prefixing the name of fruits for example plum wine, peach wine etc. Wines are of two kinds viz. dry and sweet.

Dry wines contain practically very little or no sugar, whereas sweet wines contain some sugar and taste sweet. The alcohol content of these wines ranges from 7 to 20 percent. The wines are also categorized on the basis of alcohol contents as Light, medium or strong wines



 

Different types of wines.


Type

Characterization

Champagne

It is made chiefly in France with certain varieties of grapes. Champagne is a sparkling clear wine and also made in several other countries. Generally the fermentation is allowed to proceed to completion in bottles. These bottles are specially made to withstand high pressure of gas produced during fermentation.

Port

This is fortified sweet red wine originally in Portugal, but now produced in other countries.

Muscat

It is prepared from Muscat variety of grapes in Australia, California, Italy and Spain

Tokay

It is famous fortified wine of Hungary

Sherry

Sherry is a Spanish wine, which is matured by placing the filled barrel in sunlight having a temperature of 54 to 60oC for 3 to 4 months

Perry

The wine prepared from pears is called as Perry. It can be prepared from the culled fruits and fruit trimmings of the canneries.

Orange wine

Sweetened orange juice is fermented to produce orange wine. The method of preparation is similar to that of grape wine. Orange peel oil should be minimum in the juice, otherwise its presence stop the fermentation completely.

Berry wine

The wine made from fruits like strawberry, blackberry and elderberry is known as berry wine.

Feni

Feni is a wine made from fermentation of cashew apple, in some places like Goa.

Nira

Nira is prepared from the juice of the palm tree

 

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